最 + [adjective] 最 + [adjective] + 的 + [noun] [subject] + 最 + [verb]
最 before an adjective makes it a superlative: "most" or "-est". There are no irregular forms: "best" is simply 最好.
Before a noun, 的 links them: 最好的朋友, 最贵的手机. Drop the noun and 的 stays.
最 replaces 很; the two don't stack.
Whatever the superlative is measured against comes before 最, not after.
Verbs of liking and wanting take 最 directly, and 最喜欢的 + noun is how you say "favourite".
In front of a verb, zuì hǎo最好 stops being a superlative and means "you'd better".