多少 + [noun]? 多少 + [measure word] + [noun]?
多少 asks "how many" or "how much", with no limit on the size of the answer. It goes straight before the noun.
几 expects a small number, under about ten, and always takes a measure word. 多少 expects anything. Asking 你有多少个哥哥 sounds like the family is enormous.
Unlike 几, 多少 can go straight onto the noun. Adding the measure word is also correct.
多少钱 is the standard way to ask a price. A number that is read out digit by digit – a phone number, a room number – is asked with 是多少.
Without a question, 多少 means "however much": 有多少给多少, "give however much there is".