どの is a question word meaning "which" and is used to ask about a specific item among three or more options. It always comes directly before a noun and cannot stand alone – it must modify a noun.
どの and どれ both mean "which," but they are used differently. どれ is a pronoun and stands alone without a noun, while どの is a pre-noun modifier and must always be followed by a noun.
When choosing between two options, use どちら (or どちらの + noun) instead of どの.
When there are three or more choices, use どの.
どの belongs to the こそあど series of demonstratives: