おきに goes after a number and a counter and gives the gap between one time and the next: "every five minutes", "every three meters", "every other day".
With days, weeks, months and years, and with things you count one by one – seats, lines – おきに counts what is skipped. Skipping one day gives "every other day"; skipping two gives "every third day".
一日おきに is not "every day"; that is まいにち毎日. With minutes, hours and distances there is nothing to skip, so the number is just the length of the gap: 二時間おきに is every two hours.