[verb て-form] + たまらない [verb ます-stem] + たくて + たまらない [i-adj 〜い → 〜くて] + たまらない [na-adj] + で + たまらない
てたまらない says a feeling or a sensation is so strong you can hardly bear it: "unbearably", "terribly", "dying to". It goes on the て-form: an い-adjective becomes 〜くて, a な-adjective takes で.
In a statement the feeling is the speaker's own. For someone else's, add らしい, ようだ or そうだ.
With 〜たい the pattern means "dying to". たい is an い-adjective, so it becomes たくて.
The word in front has to be something that happens to you: an emotion, hunger, heat, an itch. A deliberate action does not fit, but wanting to do it does.
All three mean "unbearably". てしょうがない is the most casual. てならない sounds formal and suits a thought or worry you can't shake, as in おもえて思えてならない. てたまらない sits between them and is the usual choice for heat, cold, pain and hunger.
These go beyond a feeling in the て-form.
Without a て-form in front, たまらない can mean "irresistible", for something good.